D—^3He聚变动力可行性研究

本文首先简要地讨论D-3He聚变的物理要求并与D-T聚变作相应的比较,然后运用目前的约束定律和第一稳定区β极限,对计划的近期ETR规模装置(如CIT,TIBER,FER,NET)进行D-3He得失相当和点火实验的可行性研究,并对高径比第二稳定区D-3He托卡马克堆进行参数学研究,最后指出潜在的缩短商用化进程可能性。     

利用浓盐酸脱苯基方法合成混合二烃基二氯化锡

利用RSnPh3(R= Me3SiCH2、EtMe2SiCH2、Bu)和浓盐酸直接混合加热反应,合成了三种混合二烃基二氯化锡,通过IR,1H NMR和MS的测定,对产物的结构进行了表征;并探讨了反应时间、温度和浓盐酸用量对该反应产率的影响.实验结果表明,该方法与其它方法比较,具有操作简单、反应速度快、环境污染小、产率较高等特点;当四烃基锡与浓盐酸的物质的量比为1:8,在97 ℃反应7 min,混合二烃基二氯化锡的产率大于70%.     

BNCT蒙特卡洛剂量计算的混合网格算法研究

在硼中子俘获治疗(BNCT)的蒙特卡洛(MC)剂量计算中,通常使用单一的网格模式,如16mm,8mm,4mm.使用细网格计算资源太大,使用粗网格,计算精度不够,为此,根据粒子穿透深度和计数量的变化梯度,采用混合网格模拟计算,达到了细网格的精度,时间仅为细网格的37%.     

Is Kano-Nucleon Interaction Consistent with Pentaquark θ^＋

The quark-delocalization colour-screening model is employed to calculate the effective potential between nucleon and kaon. The results show that the potentials are attractive in the I = 0 channel and repulsive in the I = 1 channel. The interactions are very weak between K^＋n or K^0p due to the cancellation between I = 0 and I = 1. It is possible to have a high s-wave resonance （1615 MeV）, but the width may be too wide to be observed in the experiments.     

Method for vessel attitude estimation by spatial correlation function for bottom reverberation

Under the assumption that the sea bottom is an almost-flat and randomly rough thin layer, a spatial correlation model for bottom reverberation is constructed. At high signal noise ratio, the phase of the spatial correlation function is the product of sound wave number and the vertical vector between two hydrophones. In a nominally horizontal plane, roll and pitch bring on the vertical vector between the hydrophones. Then an equation including roll, pitch and the phase of the spatial correlation function is found. If a parallelogram can be constructed by 3 hydrophones and the rat ios of its acreage to diagonals are not smaller than half of the wavelength, roll and pitch can be obtained analytically or by optimal method. However, the ranges of roll and pitch are restricted because of the phase ambiguity. Using Fisher information matrix, the Cramer-Rao lower bound is obtained. Results from computer simulation and sea test data prove the feasibility of the method.     

BNCT优化网格设计及相关算法研究

用MCNP蒙特卡罗程序模拟了硼中子俘获治疗(BNCT)3种国际基准网格模型, 并与 修正的Snyder椭球模型进行了比较. 在此基础上, 给出了一种保质量守恒、内存量少、易于产生输入文件的4种基本材料成分的BNCT网格模型. 计算结果表明, 在4mm网格下, 新模型可以达到基准模型的精度; 根据解析模型剂量随深度的变化规律, 研究构造了多网格组合模型, 在重要区域计算精度不损失的条件下, 计算时间大大缩短. 最后研究给出了一个既保证精度、又在可接受的时间内完成剂量计算的模型、样本数和相应的算法, 它基本上满足临床BNCT的要求.     

α－蒎烯／苯乙烯共聚产物微臭氧化－薄层层析分离研究

建立了一种α－蒎烯／苯乙烯共用产物分离分析微臭氧化－薄层层析法．通过标准样品的分离和ＩＲ、ＮＭＲ表征以及共聚体组分的测定，表明这种方法对α－蒎烯／苯乙烯均聚体混合物和共聚产物中均、共聚体的分离完全，样品回收率很高，解决了α－蒎烯／苯乙烯均、共聚体无法分离分析的难题．     

光学双稳性临界点的相变行为

本文详细地讨论了光学双稳性(OB)的临界现象。理论分析主要以忽略量子涨落的Fokker-Plank方程的静态解为基础。结果发现,OB的临界现象可以纳入Landau二级相变理论的框架,并且有关临界指数之间的关系也服从标度律。 关键词：     

过渡金属钼钒砷杂多化合物的合成与TPR,TPD研究

Seven transition metal molybdovanadoarsenic heteropoly compounds have been synthesized and characterized using IR, UV, TG-DTA, pH potential titration techniques. The molecular formulae of these compounds are pro-posed to be H_xM_yAsMO₁₀V₂O₄₀·zH₂O(x=1～3, y=1,2, M=Cr, Mn, Fe, Co, Ni, Cu, Zn).They are all keggin structure. Surface nature of these compounds have been investigated by temperature programmed desorption and temperature programmed reduction techniques. NH₃-TPD results show that in TPD profiles of the compounds there are two desorption peaks corresponding to weak acid sites of desorption, respectively. Desorbing activativon energy and preexponential factor of weak acid site of desorption for compounds have been calculated. H₂-TPR re-sults show that introducting transtion metal to molybdovanarsenic acid, the reduction peak temperatures of H₂-TPR shift regularly with increasing d electron numbers of transition metals. In addition, Zn and Cu heteropoly com-pounds have yet apparent effect of hydrogen spill over.     

毛细管凝胶电泳的激光光热在线检测

近年来,毛细管电泳已成为一种高效快速的微化学分离分析新技术,在无机、有机及生物化学分析中得到了广泛的应用.但毛细管的内径小,进样量在pg～ng级,给样品的检测带来新的困难.因此,发展高灵敏度的显微在线检测器,已成为毛细管电泳技术发展中的重要环节.基于各种原理的检测器研究已有报道~[1].Dovichi等曾用热透镜技术在线检测了乙腈/